Progress in Polyoxometalates-Catalyzed Water Oxidation
نویسندگان
چکیده
منابع مشابه
Visible light-induced water oxidation catalyzed by molybdenum-based polyoxometalates with mono- and dicobalt(III) cores as oxygen-evolving centers.
The Mo-based polyoxometalates containing mono- and dicobalt(III) catalyst cores, [CoMo(6)O(24)H(6)](3-) and [Co(2)Mo(10)O(38)H(4)](6-), were found to serve as O(2)-evolving catalysts in a system consisting of tris(2,2'-bipyridine)ruthenium(II) (Ru(bpy)(3)(2+)) and sodium persulfate (S(2)O) in an aqueous borate buffer solution at pH 8.0. Kinetics of O(2) evolution reveals that the higher cobalt ...
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ژورنال
عنوان ژورنال: Acta Chimica Sinica
سال: 2014
ISSN: 0567-7351
DOI: 10.6023/a13101052